Glass network engineering of yellow-emitting Ba2Sc2B4O11:Ce3+ glass ceramics for full-spectrum lighting
Peer-Reviewed Publication
Updates every hour. Last Updated: 25-Nov-2025 22:11 ET (26-Nov-2025 03:11 GMT/UTC)
As the demand for high-quality, healthy solid-state lighting (SSL) grows, violet-light-excited full-spectrum lighting has emerged as a promising solution—it avoids blue light hazards and mimics natural sunlight. However, the critical yellow luminescent materials for this scheme are extremely scarce, plagued by low violet-light absorption and poor photoluminescent quantum yield (PLQY). To address this gap, a research team developed glass network engineering for the B2O3-BaO-Sc2O3 system, successfully fabricating violet-light-excitable yellow-emitting Ba2Sc2B4O11 (BSB):Ce3+ glass ceramics (GCs) with a record PLQY of 95.0% and superior thermal, moisture, and irradiation stability. By optimizing the [BO3]/[BO4] ratio, the team promoted heterogeneous nucleation during in-situ crystallization, forming well-crystallized BSB nanocrystals (NCs) in the glass matrix. This advancement enabled the construction of LED/LD-driven full-spectrum light sources with a color rendering index (CRI) exceeding 93, accelerating the development of sun-like lighting technology.
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