Metal sulfides with seven to eight d electrons show optimal performance as catalysts for water electrolysis, as reported by researchers from Institute of Science Tokyo. In a comprehensive analysis of various metal sulfides, they identified a volcano-shaped relationship between catalytic activity and the number of d electrons in metal atoms. This newly uncovered principle will form the basis of catalyst design guidelines, accelerating the development of efficient water-splitting catalysts for green hydrogen production.

The slow kinetics and high energy consumption of the oxygen evolution reaction (OER) limit the large-scale development of electrocatalytic water splitting. Replacing OER with the glycerol oxidation reaction (GOR) and coupling it with the cathodic hydrogen evolution reaction (HER) can optimize the electrocatalytic water splitting system. Now, a research team at Wuhan University has accelerated the hydrogen transfer in the glycerol oxidation process by regulating the d-p hybridization of MnO₂, providing new insights for balancing the adsorption and activation of biomass molecules. These findings are published in SCIENCE CHINA Chemistry.

POSTECH and Jeonbuk National University Team Demonstrates First Bidirectional Asymmetric Frequency Conversion in a Single System.