Date palm trunk biochar supported nickel catalysts enable efficient CO₂ methanation at reduced hydrogen demand
Peer-Reviewed Publication
Updates every hour. Last Updated: 27-Oct-2026 05:16 ET (27-Oct-2026 09:16 GMT/UTC)
Researchers have developed sustainable biochar‑supported mono‑ and bimetallic catalysts from date palm trunk waste for CO₂ methanation. The optimal catalyst (BCNi‑3.0, 4.6 wt% Ni) achieved 58 % CO₂ conversion and 91 % CH₄ selectivity at 400 °C and 1 bar. Increasing pressure to 30 bar enhanced performance to 76 % conversion and nearly 99 % CH₄ selectivity, with stable operation over 20 h. Bimetallic NiFe catalysts promoted CO formation via the reverse water‑gas shift (RWGS) reaction, while K promotion further favored CO production. The study demonstrates that biochar from date palm trunk provides a viable, low‑cost support for CO₂ methanation with competitive performance at significantly reduced metal loading.
Researchers have developed a controllable hydrothermal synthesis strategy for spherical cerium oxide (CeO₂) abrasives with tunable particle sizes from 32 to 531 nm while maintaining excellent sphericity and dispersity. Mechanistic studies reveal that CeO₂ formation occurs via nitrateinduced oxidation of Ce³⁺, with subsequent precipitation coupled to acetate decomposition thermodynamically driving the reaction forward. Chemical mechanical polishing (CMP) tests show that 343 nm CeO₂ achieves the highest material removal rate (73.7 nm·min⁻¹) with low surface roughness (Ra = 0.31 nm). The hydrothermally synthesized CeO₂ outperforms commercial abrasives in both short and longterm polishing owing to its uniform morphology.
Researchers have developed a porous composite sponge (ZnCuCCS) by anchoring ZnS, CuS, and Zn₁₋ₓCuₓS nanoparticles onto a cellulose–chitosan matrix via a facile hydrothermal route. The material exhibits a high porosity of 88.37 %, a narrow bandgap of 1.31 eV, and excellent mechanical stability. In simulated solar irradiation, ZnCuCCS achieves a levofloxacin (LEV) removal efficiency of 90.12 %, maintaining a stable degradation rate of 72.9 % after five reuse cycles. The study elucidates the adsorption–photocatalytic degradation mechanism, demonstrating that photogenerated holes (h⁺) and superoxide radicals (O₂⁻) are the dominant active species.
Researchers have developed a bifunctional catalyst system combining ZnZrOₓ (ZZO) with silanol nest‑enriched silicalite‑1 (AS‑1) for CO₂ hydrogenation coupled with toluene alkylation. The moderate acidity of AS‑1 significantly suppresses side reactions, reducing benzene selectivity from 6.04 % (using conventional ZSM‑5) to 0.5 %, while increasing para‑xylene (PX) selectivity from 23.6 % to 33 %. Epitaxial silicalite‑1 shell coating further enhances shape selectivity, boosting PX selectivity to 44.4 %. Optimizing the spatial distribution of ZZO and AS‑1 increases toluene conversion to 16.3 %. The integrated ZZO/AS‑1@S‑1 catalyst achieves a CO₂ conversion of 9.5 %, toluene conversion of 15 %, and PX selectivity of 57.5 % under optimized conditions.
Researchers have developed a multifunctional flame‑retardant strategy for epoxy resin by incorporating polyphosphazene‑decorated hierarchical nickel phyllosilicate (NiPS@PZN) as a reinforcing and wear‑resistant filler, together with 9,10‑dihydro‑9‑oxa‑10‑phosphaphenanthrene‑10‑oxide (DOPO) as a flame‑retardant synergist. At a total loading of 6 % (1:1 mass ratio), the composite achieves a UL‑94 V‑0 rating and a limited oxygen index of 26.6 %, while total heat release, total smoke production, and CO₂ production are reduced by 10.4 %, 23.2 %, and 26.8 %, respectively. The tensile strength increases to 103.5 MPa and the minimum wear rate reaches 1.78 × 10⁻⁵ mm³·N⁻¹·m⁻¹, demonstrating a breakthrough in overcoming the traditional trade‑off between flame retardancy and mechanical/tribological properties.
Existing electrochemical biosensing systems generally rely on external computing units for data analysis. The necessity of analog-to-digital conversion and data transfer leads to high complexity, low working efficiency and concern of privacy. Zhao et al. realize the in-sensor computing in electrochemical biosensing for the first time, which uses a single neuromorphic organic photoelectrochemical transistor to simultaneously perform multi-target biosensing and artificial neural network classification. The strategy permits in-situ training using real-time data, helping solving the issue of device-to device variations. The proof-of-concept application is demonstrated by direct classification of microRNA fingerprints in real biological samples, which provides a new paradigm for simpler, faster and more secure AI-driven electrochemical biosensing.
Liquid crystals harness dynamic fluid lattice motion to activate topochemical polymerization beyond conventional geometric constraints, yielding recyclable polymers with dissipative fluorescence readout.
Superconducting diodes, which enable dissipationless one-way current flow, have long been limited by low operating temperatures and scalability. Now, writing in National Science Review, a team from Nanjing University reports scalable high-temperature superconducting diodes based on intrinsic Josephson junctions. The devices operate up to 86 K, show tunable nonreciprocity, and exhibit zero-field memory effects, providing a practical route toward energy-efficient superconducting electronics.
Researchers have developed a CoOₓ-modified Pt/Al₂O₃ catalyst that achieves outstanding performance in the dehydrogenation of perhydro-dibenzyltoluene (H₁₈-DBT), a promising liquid organic hydrogen carrier. The optimal catalyst with 1 wt% CoOₓ loading delivers a dehydrogenation degree of 93% and a hydrogen production rate of 20.98 × 10³ mol H₂·mol Pt⁻¹·h⁻¹ at 300 °C, outperforming all previously reported catalysts. However, increasing Co loading to 10 wt% causes a sharp decline in dehydrogenation degree to only 7.2%. The study reveals that amorphous CoO clusters enhance activity by increasing Pt electron density and reducing Pt particle size.