Evaporating water while removing pollutants: nanoconfinement and physical-field regulation enable efficient solar-driven water purification
Peer-Reviewed Publication
Updates every hour. Last Updated: 21-Oct-2026 11:16 ET (21-Oct-2026 15:16 GMT/UTC)
Solar interfacial evaporation has undergone rapid development in recent years, yet its overall performance has reached a plateau due to limited advances in solar-thermal materials. Herein, we propose a synergistic nano-confinement and physical-field–modulation strategy that enables concurrent acceleration of solar-driven evaporation of water and on-site remediation of organic pollutants. Implemented in hollow mesoporous carbon nanocages integrated with Fe–N4 catalytic sites and inner wall plasmonic Au nanoparticles, the system couples mesoporous confinement with localized thermal and pressure perturbations to transform bulk water into thermodynamically activated intermediate states and substantially reduce the effective vaporization enthalpy. This integrated framework delivers high evaporation rates of 2.56 kg m−2 h−1 in planar devices and 6.84 kg m−2 h−1 in 3D architectures under one-sun irradiation, with a kinetic enhanced Hertz–Knudsen–Schrage–derived evaporation coefficient. Simultaneously, the Fe–N4 sites enable non-radical peroxymonosulfate activation for ultrafast degradation of bisphenol A, achieving a rate of 182.5 L g−1 min−1. This work establishes an ingenious strategy for coupling water-state regulation and catalytic pollutant degradation to break the performance bottleneck of solar-thermal purification.
Photodynamic therapy is attractive but often compromised by tissue hypoxia. We report a photosensitizer homodimer fission mechanism that produces photosensitizer radical ion pairs without exogenous redox substrates. These pairs enable coupled water oxidation and oxygen reduction, establishing a self-oxygen-supplying reactive oxygen species (ROS) cycle. By sustaining ROS generation under hypoxia, this strategy offers a new route to overcome the longstanding oxygen limitation of conventional photodynamic therapy.
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