Anion-exchange membrane water electrolyzers (AEMWEs) for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant NiFe-based catalysts. By introducing a third metal into NiFe-based catalysts to construct asymmetrical M-NiFe units, the d-orbital and electronic structures can be adjusted, which is an important strategy to achieve sufficient oxygen evolution reaction (OER) performance in AEMWEs. Herein, the ternary NiFeM (M: La, Mo) catalysts featured with distinct M-NiFe units and varying d-orbitals are reported in this work. Experimental and theoretical calculation results reveal that the doping of La leads to optimized hybridization between d orbital in NiFeM and 2p in oxygen, resulting in enhanced adsorption strength of oxygen intermediates, and reduced rate-determining step energy barrier, which is responsible for the enhanced OER performance. More critically, the obtained NiFeLa catalyst only requires 1.58 V to reach 1 A cm⁻² in an anion exchange membrane electrolyzer and demonstrates excellent long-term stability of up to 600 h.

International researchers from a range of disciplines challenge long-held assumptions about one of the most transformative processes in human history

Scientists have found new evidence for how our fossil human relatives in South Africa may have used their hands. Research led by Samar Syeda, postdoctoral researcher at the American Museum of Natural History, together with scientists at the Max Planck Institute for Evolutionary Anthropology, the University of the Witwatersrand, University of Kent, Duke University and the National Geographic Society, investigated variation in finger bone morphology to determine that South African hominins not only may have had different levels of dexterity, but also different climbing abilities.

Gelada monkeys understand complex "conversations" involving distress calls and prosocial comforting responses, exhibiting surprise when such vocal exchanges are manipulated to violate their expectations

New poison dart frog discovered in the Amazon's Juruá River basin is blue with copper-colored legs, and represents one of just two novel Ranitomeya species in a decade