Dual-phase medium-entropy diboride-carbide ceramics with metal element exchange during sintering
Tsinghua University PressPeer-Reviewed Publication
Multiphase composition design and entropy engineering control are promising strategies to improve the properties of ultra-high temperature ceramics (UHTCs). In this study, spark plasma sintering was used to prepare fully dense dual-phase (Zr, Hf, Ta)B2-(Zr, Hf, Ta)C ceramics from self-synthesized equimolar medium-entropy diboride and carbide powders. The obtained ceramics comprised two distinct solid solution phases, the Zr-rich diboride phase and the Ta-rich carbide phase, indicating metal element exchange occurred between the starting equimolar medium-entropy diboride and carbide during sintering. The chemical driving force originating from the metal element exchange during the sintering process is considered to promote the densification process of the ceramics. The metal element exchange between the medium-entropy diboride and carbide phase significantly increased Young’s modulus of the dual-phase ceramics. Owing to the mutual grain-boundary pinning effect, fine-grained dual-phase ceramics were obtained. The dual-phase medium-entropy 50 vol.% (Zr, Hf, Ta)B2-50 vol.% (Zr, Hf, Ta)C ceramics with the smallest grain size exhibited the highest hardness of 22.4 ± 0.2 GPa. It is inferred that optimized comprehensive properties or performance of dual-phase high-entropy or medium-entropy UHTCs can be achieved by adjusting both the volume content and the metal element composition of the corresponding starting powders of diborides and carbides.
- Journal
- Journal of Advanced Ceramics