Sc3+-modified Mg-Al-Mn-Fe-O spinel ceramics enable synergistically enhanced microwave dielectric and thermosensitive properties for 6G multifunctional front-ends
Peer-Reviewed Publication
Updates every hour. Last Updated: 19-Nov-2025 20:11 ET (20-Nov-2025 01:11 GMT/UTC)
Although traditional spinel oxides exhibit excellent microwave dielectric or thermosensitive properties, achieving linear negative temperature coefficient (NTC) behaviour and stable microwave dielectric performance simultaneously across a wide temperature range remains challenging, making it impossible to meet the stringent requirements for multifunctional integration in 6G front-end devices. This study developed Sc3+-modified Mg-Al-Mn-Fe-O spinel ceramics through B-site cation doping, breaking through this performance trade-off bottleneck. On the one hand, Sc3+ inhibits the formation of oxygen vacancies and regulates the Mn/Fe valence ratio, achieving highly linear thermosensitive characteristics across an ultra-wide temperature range of 200-1000°C (B200°C/1000°C = 8367-9758 K). On the other hand, through the lattice stabilisation effect induced by Sc3+ and the octahedral site bond strength enhancement mechanism, excellent microwave dielectric properties were simultaneously obtained: low dielectric constants (εr = 8.86-10.55), ultrahigh quality factor (Q·f= 96,000-149,000 GHz), and near-zero temperature coefficient of resonant frequency (τf = -33.2 to -10.2×10-6/°C). The cylindrical dielectric resonator antenna developed based on the prepared ceramic achieved 92% radiation efficiency and 6.28 dBi gain in the 12 GHz frequency band, verifying its engineering application potential in satellite communication front-end modules.
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