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Updates every hour. Last Updated: 20-May-2026 20:15 ET (21-May-2026 00:15 GMT/UTC)
Synergistic biphasic engineering and dual-site high-entropy doping enable stable sodium storage in layered oxide cathodes
Tsinghua University PressRecently, Professor Shijian Zheng and Associate Professor Kaixiang Lei from Hebei University of Technology, in collaboration with Professor Lin Li and Dr. Xunzhu Zhou from Wenzhou University, published a research paper titled "Synergistic biphasic engineering and dual-site high-entropy doping enable stable sodium storage in layered oxide cathodes" in the journal Nano Research. In this study, a novel P2/O3 biphasic high-entropy oxide cathode material (Na0.88K0.02Ni0.24Li0.06Mg0.07Fe0.1Mn0.41Ti0.1Sn0.02O2, HEO) for sodium-ion batteries was successfully synthesized. By integrating biphasic engineering with a high-entropy strategy, this material effectively suppresses irreversible phase transitions, significantly enhances particle integrity and structural stability, and simultaneously improves the diffusion kinetics of Na⁺. Experimental results demonstrate that the cathode material maintains a high capacity retention of 82.68% after 1000 cycles, exhibiting its outstanding cycling stability.
- Journal
- Nano Research
Synergistic fluorine-nitrogen interfaces enabling stable high-voltage sulfide-based all-solid-state lithium metal batteries
Tsinghua University PressSulfide-based all-solid-state lithium metal batteries (ASSLMBs) are promising for high-energy-density and safe energy storage. But the poor compatibility of sulfide electrolytes with both high-voltage cathodes and lithium metal anodes hinders their practical application. Here, Professor Xie Jia's group from Huazhong University of Science and Technology discloses a fluorine-nitrogen synergistic interfacial engineering strategy by modifying Li5.5PS4.5Cl1.5 (LPSC) with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI). The modified LPSC electrolyte shows a high ionic conductivity of 2.88 mS/cm. Moreover, LiTFSI induced dual-functional interphases, a fluorine-rich CEI (LiF/LixPOyFz) and a fluorine-nitrogen composite SEI (Li3N/LiF/LixPOyFz), contributing to high oxidation stability (LiNi0.8Co0.1Mn0.1O2//LiIn battery retains 107% capacity retention after 13000 cycles at 15 C) and excellent lithium dendrite inhibition ability (Li//Li: CCD 3.4 mA/cm2, stably cycling 2600 h at 0.5 mA/cm2). As a result, the LiNi0.8Co0.1Mn0.1O2//Li cell with modified electrolyte demonstrates 1000 stable cycles at a high cut-off voltage of 4.5 V and wide-temperature adaptability (-20~50 ℃). This work shows a facile and effective method for constructing long-life high-energy-density sulfide based ASSLMBs.
- Journal
- Nano Research
Ultra-highly linear Ga2O3-based cascade heterojunctions optoelectronic synapse with thousands of conductance states for neuromorphic visual system
Light Publishing Center, Changchun Institute of Optics, Fine Mechanics And Physics, CAS- Journal
- Light Science & Applications
- Funder
- National Key Research and Development Program of China, NSFC for Distinguished Young Scholars, National Natural Science Foundation of China
Indirect path, direct impact: A novel patterning strategy for futuristic OLED displays
Light Publishing Center, Changchun Institute of Optics, Fine Mechanics And Physics, CAS- Journal
- Light Science & Applications
- Funder
- Ministry of Science and ICT
Single-frequency and near-single-mode fiber laser breaks kilowatt barrier for the first time
Light Publishing Center, Changchun Institute of Optics, Fine Mechanics And Physics, CAS- Journal
- Light Science & Applications
- Funder
- National Key Research and Development Program of China
Suppressing redox reactions at the nickel oxide interface to improve the efficiency and stability of perovskite solar cells
Chinese Chemical Society- Journal
- CCS Chemistry