Hydrophilic deep eutectic solvents show potential for more sustainable dissolving pulp production
Peer-Reviewed Publication
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A perspective published in the Journal of Bioresources and Bioproducts examines the emerging role of silk fibroin (SF)/polylactic acid (PLA) composite scaffolds in bone and related tissue regeneration. The review brings together evidence on material chemistry, scaffold architecture, interfacial bonding, degradation, mechanotransduction, osteogenesis, angiogenesis and immunomodulation. Rather than treating fabrication methods or biological responses separately, the authors discuss how these factors interact to determine scaffold performance. The review also assesses evidence across in vitro, animal and translational studies, concluding that substantial work remains before SF/PLA scaffolds can move toward human clinical applications.
A new perspective organizes ten frontier questions into an integrated roadmap for nuclear science and technology. The framework connects fundamental questions - from the origin of visible mass to the cosmic production of the elements - with enabling theories and facilities, practical technologies, and the long-term governance needed to sustain the field.
Early fire detection systems that are highly sensitive are essential for reducing the impact of fire disasters. However, their development still faces significant challenges due to the lack of capability for simultaneous monitoring of both temperature and gas. Herein, we propose a facile coaxial wet-spinning strategy to fabricate a dual-parameter fiber sensor capable of simultaneously detecting carbon monoxide (CO) and temperature for early combustion warning. The resulting core–sheath structured fiber consists of a CO sensing sheath made of SnO2/In2O3 heterojunction/aramid nanofiber (ANF)/silver nanowire composite with biomimetic gradient pores, an ANF isolation layer, and a temperature sensing core composed of MXene. The gradient porous sheath constructed by gradient-induced phase separation technology exhibits gradually decreasing pore sizes from outer (> 10 μm) to inner (< 3 μm) regions. This structure demonstrates a significant enhancement in the fiber sensor’s sensitivity to CO, achieving a 15% higher response compared to non-gradient porous structures (ΔR/R0 = 0.95%/ppm; detection limit of 10 ppm), with the response time reduced to 19.28 s, surpassing the response speed of most fire-warning fibers. Additionally, this fiber sensor can rapidly monitor abnormal temperature increases, enabling flame alarm functionality within 3 s. It also achieves precise real-time temperature detection within the range of 50–300 °C, exhibiting high sensitivity (20.6 μV K−1) and a strong linear correlation (R2 = 0.99). This work highlights the significant potential of gradient pore in enhancing CO sensing and offers a novel perspective for the design of ultrafast early fire-warning fiber sensors.
The incompatibility of conventional electrolytes with high-voltage cathodes and lithium metal anodes limits the performance of lithium metal batteries (LMBs). Here, an in situ cross-linked polyurethane gel electrolyte (G-P3 AR) is designed through atomic and molecular structure regulation. The polyester segments widen the highest occupied molecular orbital–lowest unoccupied molecular orbital gap, extending the electrochemical stability window to 4.97 V for compatibility with NCM811 cathodes. Polyether segments exhibit a lower Li+ binding energy, reducing the desolvation barrier and enhancing anode stability. At the atomic level, sp2-hybridized boron in the chain extender immobilizes anions (TFSI− and DFOB−) through Lewis acid–base interactions, raising the Li+ transference number to 0.78 and enabling exceptional rate capability (157.7 mAh g−1 at 2 C in the Li||NCM811 cell). Hydrogen bonding between the polymer and solvent restructures the solvation sheath, promoting inorganic-rich interphases. The Li|G-P3 AR|NCM811 cell retains 81.7% capacity after 500 cycles at 0.5 C charge/1 C discharge, demonstrating a rational electrolyte design strategy for high-performance LMBs.