Decoding the interfacial structure and functionality of an organic additive for superconformal cobalt electrodeposition
Peer-Reviewed Publication
Updates every hour. Last Updated: 27-Jul-2025 09:10 ET (27-Jul-2025 13:10 GMT/UTC)
By applying in situ ATR-SEIRAS, electrochemical measurements, DFT calculations and MD simulations, Wen-Bin Cai from Fudan University and Xiaohui Yang from Xiamen University discovered that the additive MBIS adsorbs nearly vertically on cobalt surfaces via thiolate, suppressing the faradaic efficiency of cobalt deposition. Their work also revealed that the difference in dynamic surface coverage of the additive is vital for achieving cobalt superfilling.
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