Multi-ion co-doping: Cracking the "high storage vs. high voltage" dilemma in lead-free energy storage ceramics
Peer-Reviewed Publication
Updates every hour. Last Updated: 27-Oct-2026 17:16 ET (27-Oct-2026 21:16 GMT/UTC)
In the realm of pulse power capacitors, dielectric energy storage materials are undeniably the "heart." As global demand surges for rapid charge-discharge capabilities, high operating voltages, and long service lives, these materials play a pivotal role in sectors ranging from hybrid electric vehicles to high-energy weapon ignition systems.
However, Barium Titanate (BaTiO3, or BT), the poster child for lead-free ferroelectrics, faces a classic trade-off. While blessed with high polarization strength, it has long been plagued by a "shortcoming": low breakdown strength (typically Eb<1000 kV cm−1).
It is akin to a "seesaw" dilemma: achieving high energy storage density often comes at the expense of breakdown strength, while striving for high voltage tolerance can lead to insufficient polarization. Consequently, the key scientific hurdle for researchers is how to actively construct functional nanodomain structures within the BT system while maintaining its high polarization performance.
Researchers at Shaanxi Normal University have developed a flexible electrode with atomically tuned the composition of TixCr1−xN solid-solution nanoparticles for lithium-sulfur batteries. Such cathode enhances polysulfide trapping and conversion via d-band electronic regulation, achieving high-rate capacity (801 mAh g⁻¹ at 3 C) and ultralow capacity decay (0.012% per cycle at 2 C). This work provides a practical strategy for the preparation of composite cathode in high-energy Li-S batteries.
Researchers from Jianghan University have developed a biocompatible zinc–oxygen (Zn–O₂) battery that operates stably inside the body, addressing corrosion and biosafety issues that limit traditional implantable power sources. The device uses a composite gel electrolyte to resist oxygen and moisture infiltration while maintaining excellent biocompatibility. When implanted in rats, it delivered stable voltage output sufficient to power biosensors. This work offers a safe and durable energy platform for future implantable medical devices and bioelectronic therapies.
The integration of nanotechnology with metal-based materials offers innovative strategies to significantly enhance therapeutic efficacy and targeting precision in drug delivery. Leveraging the unique properties of metal-based nanomaterials such as gold nanoparticles, iron oxide nanoparticles, and metal-organic frameworks enables the development of sophisticated platforms for targeted delivery, controlled release, and integrated theranostics. These materials support diverse applications including drug delivery, photothermal therapy, radiotherapy sensitization, immunotherapy, and multimodal therapy. The promising prospects of these technologies underscore their transformative potential in advancing personalized medicine and diagnostic approaches.
Passive radiative cooling (PRC) represents a pivotal zero-energy solution for addressing global cooling demands, the energy crisis, and carbon emission challenges. While traditional Mg2Al4Si5O18 ceramics possess significant theoretical potential owing to their wide bandgap and abundant phonon modes, their practical performance is severely constrained by phonon-polariton resonance, which compromises infrared emissivity. To surmount this bottleneck, a novel strategy combining phonon engineering and bandgap engineering is proposed. A series of Y3+-doped Mg2Al4Si5O18 ceramics were rationally designed and synthesized to effectively suppress phonon-polariton resonance and widen the bandgap, thereby significantly enhancing both atmospheric window emissivity and solar reflectivity. The optimized material exhibits exceptional daytime cooling performance, achieving a maximum temperature reduction of 16.5 °C and an average net cooling power of 113.1 W·m-2. This study presents a low-cost, eco-friendly, and highly stable inorganic ceramic solution for large-scale PRC applications, paving a new avenue for the development of next-generation sustainable cooling materials.
This work presents efficient short-wave infrared (SWIR)–emitting InP quantum dots (QDs) synthesized through controlled core nucleation and copper doping, achieving a high photoluminescence quantum yield (PLQY) of 66% at 960 nm. When integrated into a liquid waveguide luminescent solar concentrator (LSC), these QDs enabled an optical efficiency of 7.36% through optimized light management and spectral alignment with the responsivity peak of silicon solar cells, demonstrating the potential of InP QDs as a sustainable and high-performance material platform for SWIR optoelectronics.
A review paper by scientists at Shenyang Institute of Automation, Chinese Academy of Science presented a comprehensive overview of the construction, control, and application of cyborg animals composed of biological and electromechanical systems.
The review paper, published on Mar 26, 2026 in the journal Cyborg and Bionic Systems.
Entropy engineering has emerged as a promising paradigm for tailoring the electronic and photoelectric properties of materials. Although high-entropy transition metal sulfides have been achieved, entropy engineering in 2D tellurides remains challenging. In this work, we report the successful synthesis of a 1T' monolayer heptanary medium-entropy (ME) alloy (MoaWbFecCodSxSeyTez) via a one-step chemical vapor deposition method. Advanced characterizations, including scanning transmission electron microscopy, energy dispersive X-ray spectroscopy and electron energy loss spectroscopy confirm the uniform atomic-level distribution of the seven constituent elements within the alloy. The 1T' ME alloy device exhibits a high drain current of ~ 6.5 mA, which is 216 times higher than the ~ 30 μA observed in pristine 1T' MoTe2. Furthermore, the 1T' ME alloy photodetector exhibits responsivities of 27.92 A/W at 1064 nm and 63.74 A/W at 1550 nm, outperforming those of the pristine 1T' MoTe2 by more than two orders of magnitude. This remarkable enhancement is attributed to the reduced Schottky barrier (15.9 meV) at the 1T' ME alloy/electrode interface, along with the enhanced conductance (0.43 S) and reduced thermal activation energy (4.1 meV) in the 1T' ME alloy, collectively facilitating more efficient carrier injection and transport. Our work provides a distinct pathway for tailoring the properties of transition metal dichalcogenides through entropy engineering and offers valuable insights for the design of high-performance infrared photodetectors.
A new review explores the counterintuitive phenomenon of negative thermal expansion (NTE) in two-dimensional (2D) materials, where heating causes them to shrink instead of expand. The work, published in a peer-reviewed journal, synthesizes recent advances in understanding and controlling this behavior in materials like graphene and boron nitride. By leveraging mechanisms such as specific atomic vibrations and magnetic interactions, researchers are developing strategies to engineer materials with zero or custom-tailored thermal expansion, which is crucial for preventing heat-induced damage and performance drift in high-precision nanoelectronics, aerospace components, and quantum devices.
In response to dysregulated cholesterol metabolism in cancer, researchers have developed a nanozyme (AVA-COD@Fe) that depletes tumors of cholesterol and promotes ferroptosis. This strategy simultaneously inhibits cancer growth and metastasis while activating a robust antitumor immune response, which is further enhanced by anti-PD-L1 therapy to effectively combat both primary and metastatic tumors.