Ultra-high piezoelectric properties of BiFeO3-BaTiO3 lead-free piezoelectric ceramics enabled by a one-step sintering process
Peer-Reviewed Publication
Updates every hour. Last Updated: 27-Oct-2026 10:17 ET (27-Oct-2026 14:17 GMT/UTC)
High-performance piezoceramics are urgently needed for precision actuation, but conventional lead-based materials face environmental restrictions. The BiFeO₃‑BaTiO₃ (BF-BT) lead-free system offers high Curie temperature yet suffers from large leakage current and poor process stability. A team led by Prof. Bo-Ping Zhang at University of Science and Technology Beijing developed a one-step sintering method to fabricate 0.7BiFeO3‑0.3BaTiO3 ceramics, achieving a d33 of 201 pC/N, a high-field d33* of 1021 pm/V, a large strain of ~0.38%, and a Curie temperature of 501 °C. Through precise Fe non-stoichiometry defect engineering, the study reveals the temperature-dependent leakage conduction mechanisms in the BF-BT system and the synergistic role of internal bias fields on strain behavior, providing insights into defect–property relationships for lead-free piezoceramics.
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