Thermal-stable Ethylammonium doping enables customization of the emission properties of perovskite quantum dots
Peer-Reviewed Publication
Updates every hour. Last Updated: 12-Nov-2025 00:11 ET (12-Nov-2025 05:11 GMT/UTC)
All-inorganic CsPbI3 quantum dots (QDs) are regarded as promising candidates for advanced display materials due to their outstanding optoelectronic properties. However, conventional high-temperature thermal injection methods struggle with precise bandgap tuning, making it challenging to achieve pure red emission from CsPbI₃QDs. Now, in a study published in Science Bulletin, researchers from Zhejiang University of Technology have developed a thermally stable ethylammonium (EA+) doping strategy for CsPbI3 QDs, achieving Rec.2020-standard pure-red perovskite light-emitting diodes (PeLEDs) with a high external quantum efficiency exceed 26%. The key innovation lies in an in situ acid–base equilibrium reaction that generates thermally stable ethylammonium oleate. This allows for the successful synthesis of EA+-doped CsPbI3 QDs via high-temperature thermal injection, enabling precise emission tuning (630-650 nm) and exceptional spectral stability. The breakthrough opens new avenues for high-performance display technologies.
A study in National Science Review reports systematic observations of diazotroph abundance, community structure, and N2 fixation rates in the western North Pacific. Using generalized additive models, the team characterized ecological niches of key cyanobacterial diazotrophs and quantified UCYN-B’s contribution to global N2 fixation. The findings highlight UCYN-B’s pivotal role in marine N₂ fixation and provide new insights into ocean nitrogen cycle and productivity under climate change.
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Creating strongly coupled heterostructures with favorable catalytic activities is crucial for promoting the performance of catalytic reactions, especially those involve multiple intermediates. Herein, we fabricated a strongly coupled platinum/molybdenum nitrides nanocluster heterostructure on nitrogen-doped reduced graphene oxide (Pt/Mo2N–NrGO) for alkaline hydrogen evolution reaction. The well-defined Pt-containing Anderson-type polyoxometalates promote strong interfacial Pt–N–Mo bonding in Pt/Mo2N–NrGO, which exhibits a remarkably low overpotential, high mass activity, and exceptional long-term durability (> 500 h at 1500 mA cm-2) in an anion-exchange membrane water electrolyzer (AEMWE). Operando Raman spectroscopy and density functional theory reveal that pronounced electronic coupling at the Pt/Mo₂N cluster interface facilitates the catalytic decomposition of H2O through synergistic stabilization of intermediates (Pt–H* and Mo-OH*), thereby enhancing the kinetics of the rate-determining Volmer step. Techno-economic analysis indicates a levelized hydrogen production cost of $2.02 kg-1, meeting the US DOE targets. Our strategy presents a viable pathway to designing next-generation catalysts for industrial AEMWE for green hydrogen production.
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