Gradient tri-layered TGOs in MoSi2/HfO2 duplex EBCs for effective protection of SiC substrate against steam corrosion at 1500 °C for 200 h
Peer-Reviewed Publication
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The protective effectiveness of environmental barrier coatings (EBCs) for SiC-based composites is challenged by the thickening and phase transformation of the SiO2 scale, known as thermally grown oxide (TGO). In this study, a tri-layered TGOs scale, comprising cristobalite, Hf-doped SiO2 glass, and particle-reinforced Hf-Si-O glass, was formed during the oxidation of MoSi2/HfO2 duplex EBCs. The incorporation of the gradient Hf-doping and HfO2/HfSiO4 particle-reinforcement were demonstrated to effectively suppress the crystallization and phase transition of the SiO2 and mitigate internal stress within the EBCs, generating a crack-blocking effect. This effect prevented the TGOs scale from further channel crack propagation, enabled the SiC substrate with no detectable corrosion after 200 h of exposure at 1500 °C in steam, even when the TGOs thickness reached 24.5 μm. This work presents a novel strategy to simultaneously extend the service lifetime and enhance the high-temperature capability of EBCs through the tailored design of TGOs composition and structure.
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