Transparent hybrid metal halide glassy scintillators for tunable multicolor and high-resolution X-ray imaging
Peer-Reviewed Publication
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High-resolution X-ray imaging is essential for medical diagnostics, security screening, and industrial non-destructive testing. However, conventional powder-polymer composite scintillator films usually require large thicknesses to ensure sufficient X-ray attenuation and brightness, while particle aggregation and interfacial heterogeneity inevitably cause severe light scattering and reduce imaging resolution. To address this challenge, a research team developed two optically homogeneous hybrid metal halide glasses, MTP2SbCl5 and MTP2MnCl4, through a scalable low-temperature melt-quenching strategy. These transparent glass scintillators exhibit visible–near-infrared transmittance up to ~90%, near-complete X-ray attenuation at 1 mm thickness, light yields of 5819 and 19232 photons MeV⁻¹, and high spatial resolutions of 18.8 and 22.5 lp mm⁻¹, respectively. Beyond imaging, the glasses also show excellent irradiation stability, reversible glass–crystal–glass transition, low-temperature self-healing, and tunable radioluminescence from green to orange-red, opening a new pathway toward recyclable, large-area, high-resolution, and color-visualized X-ray imaging platforms.
Electrochemical nitrate reduction reaction (NO3RR) emerges as a sustainable approach for converting residual nitrate pollutants into valuable ammonia under ambient conditions, offering a promising alternative to the energy-intensive Haber-Bosch process. Compared to single-metal-site electrocatalysts, dual-metal-site (DMS) electrocatalysts show synergistic effects between adjacent metal sites, effectively regulating the electronic state and enhancing the catalytic activity and selectivity for NO3RR with multi-step proton and electron transfers. Further understanding on NO3RR is of practical significance for design of efficient DMS electrocatalysts.
Understanding the structure–activity relationship of catalysts is crucial for addressing global energy and environmental challenges. A research team led by Professor Jiangwei Zhang from Inner Mongolia University presents a comprehensive review of advanced characterization techniques—including spectroscopy, microscopy, compositional analysis, and in-situ/operando methods—that enable atomic-level insights into catalytic systems. These techniques pave the way for intelligent catalyst design and real-time reaction monitoring.
Hexagonal boron nitride (h-BN) ceramics possess high thermal conductivity, excellent electrical insulation, and good thermal and chemical stability, showing great potential for high-end electronics and thermal management. Current industrial production relies on hot pressing, which limits product size and yield with high costs. Pressureless sintering is simple, low-cost, and suitable for large or complex shapes. However, due to the extremely low self-diffusion coefficient of h-BN, densification via pressureless sintering is difficult, with relative densities typically below 90%. Therefore, achieving densification of h-BN by pressureless sintering has remained a key challenge for over half a century since its first synthesis.
Hydrogen purification is a critical challenge for clean energy. The Sun and Kang’s group have now developed a novel composite membrane using a "mortar-and-brick" strategy. This membrane combines a metal-organic framework (MOF) as the "bricks" with a hydrogen-bonded organic framework (HOF) as the "mortar," creating an all-nanoporous hierarchical structure. Hetero-MOF facilitates the hetero-nucleation, and the systematic rule of HOF’s crystal growth interfered by hetero-phase is established: suppressing the homo-nucleation, balancing nucleation driving force with molecular attachment rates, and optimizing the nutrients supplement and demand. The optimized membrane shows a 562% increase in hydrogen permeance and 241% improve in hydrogen/methane selectivity compared to a pure HOF membrane, offering a new blueprint for next-generation gas separation materials that combine easy processing with high performance.