Enhancing NO reduction to ammonia via porous aromatic frameworks: Co-modified PAF-TPP for efficient mass transfer and electrocatalytic performance
Peer-Reviewed Publication
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The electrocatalytic reduction of nitric oxide (NO) to ammonia (NH3) offers a promising strategy for simultaneously addressing industrial pollutant emissions and enabling sustainable chemical synthesis. In this study, porous aromatic frameworks (PAFs) are introduced for the first time into the NORR system, where their intrinsic porous architecture enhances NO adsorption and interfacial mass transport. By incorporating Co²⁺ ions into a tetraphenylporphyrin-derived PAF (PAF-TPP), a Co-N₄ coordinated catalyst (PAF-TPP-Co) is constructed, achieving highly efficient NO-to-NH₃ conversion. The catalyst delivers an ammonia production rate of 914.2 μg·h-1·mgcat-1 and a Faradaic efficiency of 71.3% at -0.6 V vs. RHE. A synergistic “adsorption–transport–catalysis” mechanism is proposed, providing new insight into the design of porous catalytic systems for NORR.
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