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Researchers developed nitrogen-rich supports that electronically regulate a cobalt phthalocyanine catalyst, enabling selective electrochemical conversion of CO2 into methanol under neutral conditions. The best catalyst, CoPc/TiN, achieved a methanol Faradaic efficiency of 53.28% at −1.0 V. The study reveals that support-induced electronic tuning stabilizes key intermediates and promotes the methanol pathway.
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Chinese Journal of Catalysis
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