Figure Abstract (IMAGE)

Dalian Institute of Chemical Physics, Chinese Academy Sciences

Figure Abstract

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Ce-MOFs based solid frustrated Lewis pairs (FLPs) were designed via a competitive coordination strategy using single-carboxylate ligands. Functional groups (–NH2, –OH, –Br, –NO2) modulate the Ce–CUS/Ce–OH acid–base sites, enhancing H₂ heterolytic cleavage through a “push-pull” effect. The optimized MOF-808-NH₂ achieves complete conversion of styrene and dicyclopentadiene at 100 °C and 2 MPa, providing an efficient pathway for green olefin hydrogenation catalysis.

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Chinese Journal of Catalysis

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