A Promising Strategy for Solvent‑Regulated Selective Hydrogenation of 5‑Hydroxymethylfurfural over Porous Carbon‑Supported Ni‑ZnO Nanoparticles (IMAGE)
Caption
- A porous carbon-supported Ni-ZnO nanoparticles catalyst (Ni-ZnO/AC) was synthesized by low-temperature coprecipitation, demonstrating exceptional catalytic activity and stability.
- Selective hydrogenation of 5-hydroxymethylfurfural (HMF) to 2,5-bis(hydroxymethyl)furan (97.5%) or 2,5-dimethylfuran (99.5%) is achieved over Ni-ZnO/AC catalyst by solvent-tuning.
- Solvent-catalyst interaction jointly regulates hydrodeoxygenation behavior in HMF hydrogenation by modulating rate and pathway via a hydrogen shuttle mechanism.
Credit
Rulu Huang, Chao Liu, Kaili Zhang, Jianchun Jiang, Ziqi Tian, Yongming Chai, Kui Wang.
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License
CC BY-NC-ND