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This review summarizes the operando ATR-SEIRAS and its key applications in CO2RR catalyzed by SACs. It covers topics including a brief introduction to the surface enhancement mechanism of electrochemical in situ infrared spectroscopy, the function of operando ATR-SEIRAS in investigating the mechanisms in CO2RR and methods of using spectroscopic information to determine interfacial H2O and local pH at the electrode.
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Chinese Journal of Catalysis
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